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Valery Astapenko^{1*} and Mikhail Mutafyan^{2}

^{1}Moscow Institute of Physics and Technology (National Research University), 9, Institutskiy Pereulok, Russia^{2}Sheridan College Institute of Technology and Advanced Learning, Canada

**Received:** October 31, 2022; **Published:** November 07, 2022

***Corresponding author: **Valery Astapenko, Moscow Institute of Physics and Technology (National Research University), 9,
Institutskiy Pereulok, Dolgoprudny, 141701, Russia

**DOI:** 10.26717/BJSTR.2022.47.007440

We obtained the expressions for Morse oscillator classical motion with explicit dependence on initial coordinate and velocity. These formulas provide the easy comparison with results of numerical calculations, and in addition to previous considerations, they take into account the possible different sign of initial velocity of the oscillator. The analogy between the free motion of a Morse oscillator and motion of a particle in gravitation field (i.e. the Kepler problem) is drawn up.

**Keywords: ** Bleomycin; Drug Eruptions;Dermatitis; Erythema

It is well known that the harmonic oscillator model can be employed for weakly excited mechanical systems. When excitation grows, anharmonicity begins to be noticeable and more sophisticated models should be used. One of these models is the Morse oscillator which is especially useful for the description of diatomic molecule oscillations. For example, the experimental value of the dimensionless the anharmonicity parameter for the CO molecule is xe = 0.00612. The anharmonicity parameter serves as a measure of the deviation of the real oscillator’s discrete spectrum from the equidistant approximation. In the Morse model, xe = 0.00608, so the relative error is only 0.65%. The Morse model is mostly used in quantum mechanics. Particularly, the exact wave function of a particle in the Morse potential is well-known for many decades [1]. Classical applications of the Morse model are not so numerous. To our knowledge, the first work with the exact analytical solution for the Morse oscillator’s classical motion is paper [2]. This problem was also considered 30 years later [3]. In these papers, similar expressions were obtained while using slightly different approaches. Regardless of the abovementioned articles, we have also found analytical expressions for the free motion of the Morse oscillator [4]. Our formulas were obtained using the energy conservation law without solving any differential equations. They also were written in another form when compared with the results of [2,3]. Below we introduce our consideration of the problem which provides some additions to previous results [2,3]. Moreover, we demonstrate the analogy between the free motion of a Morse oscillator and motion of a particle in a gravitation field.

The potential energy of Morse oscillator is given [1] by the following formula:

where *D* is the binding energy, *k* is the parameter of the
potential, x is the displacement of the oscillator’s coordinate
from its equilibrium position. In the case of a diatomic molecule,

**Figure 1** The Morse potential energy plotted using the parameters of a CO molecule (solid thick curve) and its corresponding harmonic approximation (dash-dotted curve).

Consider the free motion of a Morse oscillator for given total
energy *ε* measured from the bottom of a potential well (Figure
1). It is convenient to introduce a dimensionless displacement of
the coordinate from its equilibrium position, *y = k x* , and dimensionless
time,

Using such definitions, the Morse oscillator’s motion equation can be written as the following:

Note that the dimensionless Eq. (2) does not contain the
binding energy *D* and the parameter of the potential *k* , so it is
universal for the given type of potential energy. To determine the dependence *y(τ)*, it is convenient to use the law of conservation of energy, which in dimensionless variables can be written as the
following equation:

where

is dimensionless energy. Here, the first term on the left side of the equation corresponds to the kinetic energy, while the second and the third terms represent the potential energy. The solution of (3) depends on the magnitude of the dimensionless energy . Three cases, which correspond to three motion modes, can be differentiated: the first one, when , the second, when , and the third, when . Below it will be demonstrated that the first case corresponds to the finite motion, i.e., oscillations of the Morse oscillator, while the latter two cases correspond to the infinite motion, i.e., the expansion mode. For a finite movement which corresponds to the oscillatory mode, . Solving (3), the following dependence is obtained [3, 4]:where *τ _{0}* is the integration constant (which we will later
assume is zero) and

The (4) yields the dependence *y(τ)* in an implicit form. To
obtain the explicit form of the function *y(τ)*, the integral on the
right-hand side of (4) needs to be calculated and then y needs to
be expressed via the dimensionless time *τ* . The resulting formula
is

is the initial phase of the oscillations dependent on initial displacement

.The sign in front of the square root depends on the sign of initial velocity of the oscillator

.The resulting expression is valid while the dimensionless energy

. This corresponds to the negative part of the energy spectrum. The harmonic approximation is valid for low excitation energies of the Morse oscillator, i.e., for . The Eq. (6) then turns into the well-known expression for free oscillations of a harmonic oscillator. Using the dimensionless variables, it can be written in the form:From (5) and (7) it follows that the oscillation period for the Morse oscillator depends on the energy and is given by the expression

**Figure 2** The Morse oscillator’s motion for various values of dimensionless energy: ε~ = 0.1 (solid curve), ε~ = 0.3 (dotted curve), and ε~ = 0.6 (dashed curve) and for the negative initial velocity.

It should be noted that this is the period of anharmonic oscillations. The motion of the Morse oscillator, defined as the dependence of the dimensionless coordinate on the dimensionless time, are shown in (Figure 2) for different values of the dimensionless energy. It is noticeable that when the energy is low, the oscillations are symmetrical in accordance with the Eq. (7) which describes the harmonic oscillator’s motion. With energy increasing, the amplitude of oscillations scales up, the motion becomes asymmetric and anharmonic and oscillation period increases. This anharmonicity is explained by the Morse potential energy’s asymmetry with respect to the equilibrium coordinate (x = 0 in (Figure 1)) – this asymmetry does is not exist in the harmonic oscillator’s potential energy.

The Eq. (8) suggests that with the increasing energy, the period
also increases, and with *ε →D, T ^{(Morse)} →∞* Thus, upon
reaching the boundary of the negative part of the spectrum where

where

is the value of the dimensionless coordinate at the initial moment of time. It is required that ln so that the radicand in the right side of equality (9) is non-negative. The sign plus in (9) relates to positive initial velocity and sign minus to the negative one. When the time tends to infinity,**Figure 3** The Morse oscillator’s infinite motion for various dimensionless energies and different signs of initial velocity: solid curve – ε~ =1, 0 0 y < , dotted curve – ε~ =1, 0 0 y > ; dashed curve – ε~ =1.5 , 0 0 y < , dotted-dashed curve – ε~ =1.5 , 0 0 y > .

where

is the constant determined by the initial conditions, and

is the dimensionless velocity at infinity. Upper sign in (11) corresponds to negative initial velocity and lower one to the positive initial velocity. From the (10) it follows that when time tends to infinity , the oscillator’s coordinate . This suggests that when the Morse oscillator’s total energy is positive, i.e., when , the expansion happens linearly in time. The time dependences of the Morse oscillator’s infinite motion are demonstrated in Figure 3. For these graphs, the initial coordinate is assumed to be equal to zero,The three described modes of Morse oscillator’s one-dimensional motion have an extended analogy in the three-dimensional case. Their counterpart is the motion of a particle in a three-dimensional Coulomb attraction field or in a gravitational field. Any movement in such a field can occur in three modes: in an ellipse when the energy is negative, in a parabola when the energy equals to zero, or in a hyperbola when the energy is positive. This motion is known as the Kepler problem. The role of the dimensionless energy

in the case of the Kepler problem is determined by the square of the orbit’s eccentricityIndeed, in the Kepler case, the total energy

, while in the case of the Morse oscillator, . As it is known [5], whenThe analytical formulas describing the Morse oscillator’s free motion in dimensionless variables have been derived and analyzed. In addition to the previous results [2,3] we took into account different signs of the initial oscillator’s velocity. Further to that, our formulas explicitly depend on the initial conditions, which makes it easy to compare them with the results of a numerical solution to this problem. The study involved three motion modes: oscillatory, infinite with zero energy, and infinite with positive energy. The analysis involved motion characteristics of each of these cases. For the oscillatory mode, the relation between the period of a Morse oscillator and its energy has been established. The analogy between the Morse oscillator’s free motion and the motion of a particle in a gravitational potential, i.e., the Kepler problem, has been demonstrated.

The authors declare that they have no competing interests.

The authors wrote, read and approved the final manuscript.

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